Interpenetrated and polythreadedCoII-organic framework as asupercapacitorelectrode material with ultrahigh capacity and excellentenergydelivery efficiency

Author: 张明智     Updated: 2018-09-12    Read:

Interpenetrated and polythreadedCoII-organic framework as asupercapacitorelectrode material with ultrahigh capacity and excellentenergydelivery efficiency

Kuaibing Wang,†,‡ Xiaoran Cao,Saier Wang,Wenjia Zhao,JiangyanXu, Zikai Wang and Hua Wu†,*

ACS Applied Materials & Interfaces, 2018, 10(10), 9104-9115. (IF = 8.097)

 

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Three novel CoII-based MOFs, namely [Co(HTATB)(o-bix)]·H2O,Co(HTATB)(m-bix) and Co(HTATB)(m-bix)·2H2O,have been synthesizedthrough variation of flexible N-donor ligand and inorganic anions, and directly applied the as-synthesized crystalline MOFs as electrode materials for SCs. These Co-MOFs with 3D interpenetrated, 2D layered and extended 3D networks exhibit high gravimetric capacitance, better rate capability, long-term cycling life, and excellent energy delivery efficiency.